Determination of Iron (III) as Tropolone-5-sulfonic Acid Chelate

Chitosan Capped Silver Nanoparticles as Colorimetric Sensor for the Determination of Iron(III)

A selective, simple and low-cost method for the colorimetric determination of Fe3+ ions based on chitosan capped silver nanoparticles (Chit-AgNPs) was presented. Chitosan is a cationic polyelectrolyte and possesses amino and hydroxy groups which make it widely used as a capping agent for Ag NPs. The synthesized chitosan capped silver nanoparticles with excellent colloidal stability were charact...

5-(Phenyl­diazen­yl)tropolone

THE TITLE COMPOUND [SYSTEMATIC NAME: (E)-2-hy-droxy-5-(phenyl-diazen-yl)cyclo-hepta-2,4,6-trien-1-one], C(13)H(10)N(2)O(2), is essentially planar with an r.m.s. deviation of 0.036 (2) Å and a dihedral angle of 1.57 (8)° between the phenyl and tropolone rings. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen bonds into inversion dimers. The dimers are further connected by C-H⋯O h...

Oxygen catalyzed mobilization of iron from ferritin by iron(III) chelate ligands.

Tridentate chelate ligands of 2,6-bis[hydroxy(methyl)amino]-1,3,5-triazine family rapidly release iron from human recombinant ferritin in the presence of oxygen. The reaction is inhibited by superoxide dismutase, catalase, mannitol and urea. Suggested reaction mechanism involves reduction of the ferritin iron core by superoxide anion, diffusion of iron(II) cations outside the ferritin shell, an...

Phenylbiguanide-p-Sulfonic Acid as an Analytical Reagent for the Colorimetric Determination of Nickel

p-Toluene-sulfonic acid, cholesterol determination, and explosions.

HAVE BEEN USING the method of Pearson, Stern, and McGavack (1) for the determination of cholesterol for some time. It has proved to be a convenient and accurate procedure and the reaction had always gone smoothly. One day recently, however, the tubes were set up for the determination as usual, using a freshly prepared solution of p-toluenesulfonic acid. Solutions made from the same bottle of so...